A carbon nitride and ruthenium complex system with 4 different Ru complexes are reported in this article. The authors state that these results are "the best values that have been reported for heterogeneous photocatalysts for CO2 reduction under visible-light irradiation to date." I am trying to design and synthesize homogeneous catalysts, but I always have great interest in heterogeneous systems.
Below you can see their CO2 reduction abilities.
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