Friday, May 22, 2015

Ammonia Activation by a Nickel NCN-Pincer Complex #chempaper 218

This is an interesting article on ammonia activation. We often don't think about how ammonia is needed as a substrate. It is always good to remember. The authors give some spectroscopic evidence on the equilibrium between coordinated ammonia and amido species, but unfortunately there is no crystal structure or an N-H IR stretch reported. 

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